Classical Kinetic Theory of Fluids (Wiley, 1978). Qualitative properties of shear viscosity in liquids. New possibilities provided by the analysis of the molecular velocity autocorrelation function in liquids. Nature of the kinematic shear viscosity of low-molecular liquids with averaged potential of Lennard-Jones type. Nature of self-diffusion and viscosity in supercooled liquid water. Upper temperature limit for the existence of living matter. Specific features of self-diffusion in water.Zh. The character of the thermal motion of water molecules according to the data of quasi-elastic incoherent slow neutron scattering. Diffusion and nuclear spin relaxation in water. Self-diffusion coefficient of supercooled water. Dielectric relaxation of water and heavy water in the whole fluid phase. Surprisin properties of the kinematic shear viscosity of water. Nature of the kinematic shear viscosity of water. Liquid State Physics – A Statistical Mechanical Introduction (Cambridge Univ. The Structure and Properties of Water (Oxford Univ. New results in the theory of collective self-diffusion in liquids. Models and equations for atomic transport coefficients of liquid metals: Viscosity and self-diffusivity. Samoilov, Structure of Aqueous Electrolyte Solutions and the Hydration of Ions (Consultants Bureau, 1965). Kinematic shear viscosity of liquid alkaline metals. Experimental study of the viscosity of simple substances on the saturation line and under pressure. NIST Chemistry WebBook, NIST Standard Reference Database Number 69. ĬRS Handbook of Chemistry and Physics: A Ready-Reference Book of Chemical and Physical Data. Viscosity, plasticity, and diffusion as examples of absolute reaction rates. Kinetic Theory of Liquids (Dover, 1955).Į.N. Lifshitz, Fluid Mechanics (Pergamon Press, 1993). Eine neue Bestimmung der Molekuldimensionen. Thermal motion in water-electrolyte solutions according to quasi- elastic incoherent neutron scattering data. Neutron studies of water self-diffusion in aqueous electrolyte solutions. Self-diffusion of water in aqueous solutions of singly charged electrolytes. On the collective nature of thermal motion in fluids. Hydrodynamic asymptotics of autocorrelation function of molecular velocity in classical fluid. Role of the collective self-diffusion in water and other liquids. Physics of Liquid Metals (Vyshcha Shkola, Kyiv, 1979) (in Russian). In all cases, the preference is given to qualitative arguments.Į.I. The immanent contradiction of exponential temperature dependences for the viscosity and self-diffusion coefficients is proved. Sound arguments are proposed concerning the inadequacy of the activation mechanism of thermal molecular motion in low-molecular liquids. Manifestations of the collective vortical transport of molecules as specific features in the time dependence of the root-mean-square displacement of molecules are discussed. The both components have a collective nature, they are genetically related to each other and differ only by their scales: the former is mesoscopic, the latter is nanoscopic. The self-diffusion coefficient in the fluids of all indicated types is considered to be the sum of two components: one of them is associated with the transfer of molecules by hydrodynamic vortex modes, and the other is generated by the circulatory motion of local molecular groups. The particular attention is paid to atomic fluids (such as argon), liquid metals, and associated fluids (such as water). The nature of the self-diffusion in low-molecular fluids is discussed. Self-diffusion coefficient, shear viscosity, molecular liquids Abstract
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